you cant have more than 2 whatsapp numbers on a single phone
you would have to reset whatsapp on your wifes phone, the easiest way that i know how assuming she has a different number (eg you didnt give her your sim as well) would be to simply sign in to whatsapp on your new phone with old number - this would break the link on the old phone and require a new account/number to be used to login/signup (note that its possible to use the old number again but it would break the link on the new phone as you cant have your whatsapp number active on more than 1 device either)
if thats not possible/doable then you should be able to just remove the app completely from the phone unless she wants to use it?
whatsapp is tied to your number so if the number stayed with the phone you cant really move the whatsapp account to the new phone